The Reaction of Oxygen Atoms with Dimethyl Ether
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چکیده
منابع مشابه
The reaction of protonated dimethyl ether with dimethyl ether: temperature and isotope effects on the methyl cation transfer reaction forming trimethyloxonium cation and methanol.
Fourier transform ion cyclotron resonance mass spectrometry has been used to study the temperature and deuterium isotope effects on the methyl cation transfer reaction between protonated dimethyl ether and dimethyl ether to produce trimethyloxonium cation and methanol. From the temperature dependence of this bimolecular reaction it was possible to obtain thermodynamic information concerning the...
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Dimethyl ether reaction kinetics at high temperature were studied in two different flow reactors under highly dilute conditions. Pyrolysis of dimethyl ether was studied in a variable-pressure flow reactor at 2.5 atm and 1118 K. Studies were also conducted in an atmospheric pressure flow reactor at about 1085 K. These experiments included trace-oxygenassisted pyrolysis, as well as full oxidation...
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A synthesis of ±-cherylline dimethyl ether is reported. The key steps involved are Michael-type addition, radical azidonation of an aldehyde, Curtius rearrangement, and reduction of an isocyanate intermediate followed by Pictet-Spengler cyclization.
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1966
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.39.1643